Environmental issues: The stability of the 1:1 hydrogen-bonded complex formed between tri-n-butylphosphine oxide (A) and perfluoro-tert-butyl alcohol (DH) has been measured in a range of solvents. The association constants (Kexpt) span five orders of magnitude and are predicted (Kpred) remarkably accurately by a simple solvent competition model (see picture).
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Cook et al. (2007) studied this question.
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