The gasdynamic behavior of fluids is inverted if a certain thermodynamic property Λ ≡ ρ3c4(∂2υ/∂P2)8/2 is negative. Several different methods of calculation, based on published thermodynamic data and standard equations of state, yield Γ<0 for relatively complex organic compounds.
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Lambrakis et al. (1972) studied this question.
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