Boosting Lithium Storage Properties of MOF Derivatives through a Wet‐Spinning Assembled Fiber Strategy

Graphene composite fibers are of great importance in constructing electrode materials with high flexibility and conductivity for energy storage and electronic devices. Integration of multifunctional metal–organic frameworks (MOFs) into graphene fiber scaffolds enables novel functions and enhanced physical/chemical properties. The close‐packed and aligned graphene sheets along with the porous MOF‐derived structures can achieve excellent lithium storage performance through synergetic effects. In this work, a facile and general strategy is demonstrated for the preparation of MOF/graphene oxide (GO) fibers, which serve as precursors for the subsequent preparation of porous metal oxide/reduced graphene oxide (rGO) composite fibers. The obtained composites, for example, porous Fe 2 O 3 /rGO and Co 3 O 4 /rGO fibers, possess unique features of MOF‐derived porous structures and excellent electrical conductivity. When tested as anode materials for lithium‐ion batteries in coin cells, the MOF/GO fiber‐derived porous metal oxide/rGO composite fibers exhibited high specific capacity, excellent rate capability and cycling performance. Moreover, a flexible fiber battery was fabricated based on the Fe 2 O 3 /rGO composite fiber, which demonstrates its potential application for flexible electronic devices.