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September 25, 2008Nano Letters190 citationsOpen Access

Low-Temperature Nanocrystal Unification through Rotations and Relaxations Probed by in Situ Transmission Electron Microscopy

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MHMarijn A. van HuisLKLucas T. KunnemanKOKarin Overgaag

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Abstract

Through the mechanism of "oriented attachment", small nanocrystals can fuse into a wide variety of one- and two-dimensional nanostructures. This fusion phenomenon is investigated in detail by low-temperature annealing of a two-dimensional array of 10 nm-sized PbSe nanocrystals, in situ in the transmission electron microscope. We have revealed a complex chain of processes; after coalescence, the connected nanocrystals undergo consecutive rotations in three-dimensional space, followed by drastic interfacial relaxations whereby full fusion is obtained.

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Cite This Study

Huis et al. (2008) studied this question.

synapsesocial.com/papers/6a62a0db7fd4bc433b96a436https://doi.org/10.1021/nl8024467
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