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June 14, 2010Angewandte Chemie International Edition257 citations

Expanding the Scope of Metal‐Free Catalytic Hydrogenation through Frustrated Lewis Pair Design

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GEGábor ErősMHMehdi HasanIPImre Pápai

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Abstract

No metal causes frustration: Based on a conceptual framework, novel frustrated Lewis acid–base catalyst systems with orthogonal reactivity have been developed. Aside from enhanced functional-group tolerance, unique chemoselectivity can be achieved in catalytic metal-free hydrogenations (see scheme).

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Erős et al. (2010) studied this question.

synapsesocial.com/papers/6a62a303fe5b6bd6fe96b25chttps://doi.org/10.1002/anie.201001518
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