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generation. The CV features are used to prepare H adsorption and absorption isotherms that are then used in thermodynamic data analysis. Modeling of the experimental results demonstrates that, upon H adsorption and absorption, Pd-NPs develop a core-shell-skin structure, each with its unique H loading. The electrochemical results obtained for octahedral Pd-NPs are compared to analogous data obtained for cubic Pd-NPs with a similar size as well as for larger cubic Pd-NPs and bulk materials under gas-phase conditions.
Zalineeva et al. (Fri,) studied this question.