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May 5, 2022Physica Scripta6 citationsOpen Access

Tailoring of the electrochemical stability and dielectric behaviour of inorganic matrix-based ionogels

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SGSarvesh Kumar GuptaAGAbhishek Kumar GuptaRYRajesh Kumar Yadav

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Abstract

Abstract Silicon dioxide (SiO 2 ), lithium salt (lithium perchlorate, LiClO 4 ), ionic liquid (IL; 1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, EMIMTFSI), and succinonitrile (SCN)- based ionogels (IGs) are synthesized using cost-effective non-hydrolytic sol-gel (NHSG) method. The electrochemical stability and electrical properties are associated with their molecular structures. The electrochemical stability of the IGs (I1, I2, and I3) was studied using the highest occupied molecular orbital (HOMO) & lowest unoccupied molecular orbital (LUMO) methods. AC impedance spectroscopy was used to illustrate the electronic properties of the prepared IGs. The dielectric characteristics of the synthesized IGs were studied at various temperatures and frequencies. The dielectric constant ( ε ′), dielectric loss or dissipation factor ( ε ″), tangent loss (tan δ ), electric modulus (M′ and M″), and AC conductivity ( σ ac ) of SiO 2 /IL based IGs (I1, I2, and I3) were investigated.

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Cite This Study

Gupta et al. (2022) studied this question.

synapsesocial.com/papers/6a6304a8aca57fe965287cadhttps://doi.org/10.1088/1402-4896/ac6d20
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