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Examines catalytic activity and durability in gold nanoparticles, suggesting effective ligand strategies.
powder, which is required for deprotonating BnOH, acted as heterogeneous catalysts in 1,2-dichloroethane at 60 °C. Of the three AuNP catalysts, the TDEP-protected AuNPs exhibited the greatest activity per exposed Au atoms and the longest lifetime. Conversely, the DPPE- and TPP-protected AuNPs exhibited poorer performance in terms of activity and durability, respectively. This work provides a rational ligand design strategy that balances the activity and durability of metal NPs.
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Wu et al. (2025) studied this question.
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