Two Cd(ii) boron imidazolate frameworks (/) with different topologies have been synthesized by the targeted assembly of aromatic carboxylate, tetradentate imidazolate ligands, possessing tunable luminescence emission properties. Hydroxy-functional neutral shows an obvious blue shift of luminescence after loading Ag nanoparticles (NPs) while the first reported anionic in the BIF system with blue emission can tune the white-light emission via doping mixed Ln(3+) in an appropriate ratio (Ln = Eu and Tb).
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Liu et al. (2016) studied this question.
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