Two new four-connected metal imidazolates with an unprecedented four-connected topology have been synthesized and structurally characterized. TIF-1Zn (see figure) exhibits permanent microporosity and has high thermal stability. It features unusual topological features, such as 3- and 16-rings and multidimensional large pore channels, which underlines the rich synthetic and structural chemistry of imidazolate-based porous frameworks that are yet to be explored.
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Wu et al. (2008) studied this question.
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