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A unified theory of phonon dispersions and piezoelectricity in bulk and multilayers of hexagonal boron nitride (h-BN) is derived. The dynamical matrix is calculated on the basis of an empirical force constant model of intralayer valence and interlayer van der Waals interactions. Coulomb interactions are calculated by Ewald's method, adapted for the three-dimensional (3D) and the multilayer case. The deformation of the ionic charge distribution with long-wave lattice displacements is taken into account. Special attention is devoted to the nonanalytic long-range Coulomb contribution to the dynamical matrix which is different for the 3D crystal and the multilayer case. Consequently there is a splitting of the transverse optical (TO) and longitudinal optical (LO) phonon branches of E₁ₔ symmetry and a discontinuity of the A₂ₔ branch at the point in 3D h-BN. No such splitting and discontinuity at are present in multilayer crystals with a finite number N of layers. There a diverging bundle of N overbending optical phonon branches emerges from. Born's long-wave theory is applied and extended for the study of piezoelectricity in layered crystals. While 3D h-BN and h-BN multilayers with an even number of layers (symmetry D₆₇) are not piezoelectric, multilayers with an uneven number of Nₔ layers (symmetry D₃₇) are piezoelectric; the piezoelectric coefficient e₁, ₁₁ is inversely proportional to Nₔ.
Michel et al. (Thu,) studied this question.