Empfindliche Substrate wie Alkohole, Olefine und Sulfide, die unter gewöhnlichen Baeyer-Villiger-Bedingungen elektrophile Oxidationen eingehen würden, bleiben in einer hoch chemoselektiven katalytischen Baeyer-Villiger-Oxidation unversehrt (siehe Schema). Die Flavin-Verbindung [DMRFlEt]+[ClO4]− (blau) katalysiert die aerobe Baeyer-Villiger-Oxidation in Gegenwart von Zinkstaub. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2005/z462429_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
No takes yet. Share an insight, caveat, or question.
Imada et al. (2005) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: