Novel bis(acetylacetonato)ruthenium(II) complexes bearing the 6-diphenylphosphino- N -pivaloyl-2-aminopyridine and 3-diphenylphosphinoisoquinolone ligands were synthesized. Molecular structures of these complexes were studied in solution and also in the solid state, and unusual hydrogen-bonding patterns were identified. The prepared compounds constitute active catalysts for the hydration of nitriles to amides under neutral conditions.
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Šmejkal et al. (2007) studied this question.
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