The origin bands of the A 2Pi-X 2Pi electronic transition for three new linear polyacetylene cation chains, HC12H+, HC14H+, and HC16H+, have been recorded in the gas phase at approximately 30 K, located at 924.7, 1034.6, and 1144.0 nm. The absorption spectra were observed using a two-color two-photon ion-photodissociation experiment that utilizes the cooling capabilities of a 22-pole ion trap. Such spectra allow a direct comparison between laboratory and astrophysical data; however, no matches were found between the experimentally determined origin bands and the known diffuse interstellar bands.
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Dzhonson et al. (2007) studied this question.
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