Sub-Picosecond IR Study of the Reactive Intermediate in an Alkane C−H Bond Activation Reaction by CpRh(CO)₂

John B. Asbury; Hirendra N. Ghosh; Jake Yeston; Robert G. Bergman; Tianquan Lian

doi:10.1021/om980194f

July 9, 1998Organometallics

Sub-Picosecond IR Study of the Reactive Intermediate in an Alkane C−H Bond Activation Reaction by CpRh(CO)₂

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Key Points

The research aims to identify the reactive intermediate in cyclohexane C−H bond activation using infrared spectroscopy.
Sub-picosecond infrared spectroscopy was employed.
The reaction involved CpRh(CO)2 as a catalyst.
Cyclohexane was used as the substrate to investigate the activation.
Identified the reactive intermediate as the cyclohexane solvate η5-CpRh(CO)(C6H12).

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Implication

Identifies reactive intermediate in cyclohexane C−H bond activation, implying advances in molecular reaction understanding.

Abstract

The reactive intermediate in a cyclohexane C−H bond activation reaction by CpRh(CO) 2 has been identified as the cyclohexane solvate η 5 -CpRh(CO)(C 6 H 12 ) by sub-picosecond infrared spectroscopy.

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Asbury et al. (1998) studied this question.

synapsesocial.com/papers/6a6a49b347a1bfb288f2aef7 https://doi.org/10.1021/om980194f

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Sub-Picosecond IR Study of the Reactive Intermediate in an Alkane C−H Bond Activation Reaction by CpRh(CO)₂

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Abstract

Discussion

Cite This Study

Sub-Picosecond IR Study of the Reactive Intermediate in an Alkane C−H Bond Activation Reaction by CpRh(CO)₂

Key Points

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Implication

Abstract

Discussion

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