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We report the synthesis of racemic macrocyclic molecular carbon imides, (±)-C2BNDI and (±)-C3BNDI, using 1,1′-bi(naphthyl-4,5-dicarboximides) ( BNDI ) as a building block. Single-crystal analysis revealed a twisted saddle-shaped π-framework for (±)-C2BNDI . Both macrocycles exhibit strong emission, with (±)-C2BNDI showing strong fluorescence (quantum yield = 100%) in nonpolar solvents. After chiral resolution, enantiopure (+)- and (−)- C2BNDI is found to exhibit a | g lum | value of 3.3 × 10 –3 and a high CPL brightness of 63.9 M –1 cm –1 . This study introduces a new class of chiral conjugated macrocycles with outstanding luminescent and chiroptical properties, offering promising opportunities for future applications in photonic and optoelectronic materials.
Wang et al. (Wed,) studied this question.