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Sulfinylation of organic compounds to sulfinamides is an attractive means to access various important sulfur(VI) compounds through follow-up oxidative reactions. Herein, we report a photoredox-enabled arene sulfinaylation, processing through aryl thianthrenium (Ar-TT + ) salts. High regio- and chemoselectivities of arene thianthrenation leverage structural diversity into the corresponding sulfinamides. Follow-up reactions and mechanistic investigations were performed in the study.
Patel et al. (Thu,) studied this question.