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The chromatographic behavior of roxithromycin, midecamycin, erythromycin, azithromycin, and erythromycin ethylsuccinate has been studied by salting-out thin-layer chromatography (SOTLC) with cellulose as a adsorbent and aqueous ammonium sulfate solutions of different concentration as mobile phases. Hydrophobicity was determined from the linear relationships between solute RM values and the ammonium sulfate content of the mobile phase. Hydrophobicity values RM0 and C0 were calculated on the basis of the results obtained. Lipophilicity determined in this way was correlated with calculated log P values.
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Tosti et al. (2005) studied this question.
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