Two novel isostructural 3d–4f microporous heterometal–organic frameworks (HMOFs) with high acid/base stability were constructed based on a polydentate carboxylate ligand. Luminescent studies showed that one of the new HMOFs displayed high-sensitivity luminescent sensing functions for BTEX (benzene, toluene, ethylbenzene, xylenes), particularly for ethylbenzene. This is the first observation of a 3d–4f HMOF as a chemical sensor for BTEX.
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Zhang et al. (2014) studied this question.
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