The Suzuki‐Miyaura type coupling reaction of aryl halides with triphenylborane‐pyridine was described. The reaction can be catalyzed by Pd(OAc) 2 (5 mol%) in presence of Cs 2 CO 3 at 50°C or 80°C, and functionalized biaryls were obtained in good to excellent yields. This protocol is general and can tolerate a wide range of functional groups.
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Yang et al. (2012) studied this question.
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