One of the extremely rare thiolatovanadium(II) complexes, [V(tmeda)(pyt)2] (1) is formed in the reaction of sodium pyridine-2-thiolate [Na(pyt)] with [VCl2(tmeda)2]. The octahedral structure of 1 is distorted because of the small bite angle of the pyt− ligand. In both dinuclear complexes [Na(thf)2V(pyt)4] and [V2O2(pyt)4] (2) the pyt− ligand has an unusual μ-η1:η2 bonding mode, but in 2 the pyt− bridge is unsymmetric.
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Reynolds et al. (1992) studied this question.
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