Theory of Majorana Zero Modes in Unconventional Superconductors

Abstract Majorana fermions are spin-1/2 neutral particles that are their own antiparticles; they were initially predicted by Ettore Majorana in particle physics but their observation still remains elusive. The concept of Majorana fermions has been borrowed by condensed matter physics, where, unlike particle physics, Majorana fermions emerge as zero-energy quasiparticles that can be engineered by combining electrons and holes and have therefore been called Majorana zero modes. In this review, we provide a pedagogical explanation of the basic properties of Majorana zero modes in unconventional superconductors and their consequences in experimental observables, putting a special emphasis on the initial theoretical discoveries. In particular, we first show that Majorana zero modes are self-conjugated and emerge as a special type of zero-energy surface Andreev bound states at the boundary of unconventional superconductors. We then explore Majorana zero modes in 1D spin-polarized p-wave superconductors, where we address the formation of topological superconductivity and the physical realization in superconductor–semiconductor hybrids. In this part we highlight that Majorana quasiparticles appear as zero-energy edge states, exhibiting charge neutrality, spin-polarization, and spatial nonlocality as unique properties that can already be seen from their energies and wavefunctions. Next, we discuss the analytically obtained Green’s functions of p-wave superconductors and demonstrate that the emergence of Majorana zero modes is always accompanied by the formation of odd-frequency spin-triplet pairing as a unique result of the self-conjugate nature of Majorana zero modes. We finally address the signatures of Majorana zero modes in tunneling spectroscopy, including the anomalous proximity effect, and the phase-biased Josephson effect.