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A population of binary black hole mergers has now been observed in gravitational waves by Advanced LIGO and Virgo. The masses of these black holes appear to show evidence for a pileup between 30 and 45 M-circle dot and a cutoff above similar to 45 M-circle dot. One possible explanation for such a pileup and subsequent cutoff are pulsational pair-instability supernovae (PPISNe) and pair-instability supernovae (PISNe) in massive stars. We investigate the plausibility of this explanation in the context of isolated massive binaries. We study a population of massive binaries using the rapid population synthesis software COMPAS, incorporating models for PPISNe and PISNe. Our models predict a maximum black hole mass of 40 M-circle dot. We expect similar to 10% of all binary black hole mergers at redshift z = 0 will include at least one component that went through a PPISN (with mass 30-40 M-circle dot), constituting similar to 20%-50% of binary black hole mergers observed during the first two observing runs of Advanced LIGO and Virgo. Empirical models based on fitting the gravitational-wave mass measurements to a combination of a power law and a Gaussian find a fraction too large to be associated with PPISNe in our models. The rates of PPISNe and PISNe track the low metallicity star formation rate, increasing out to redshift z = 2. These predictions may be tested both with future gravitational-wave observations and with observations of superluminous supernovae.
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