Superhydrophobic Silica Aerogels and Their Layer-by-Layer Structure for Thermal Management in Harsh Cold and Hot Environments

Personal thermal management (PTM) materials have recently received considerable attention to improve human body thermal comfort with potentially reduced energy consumption. Strategies include passive radiative cooling and warming. However, challenges remain for passive thermal regulation of one material or structure in both harsh hot and cold environments. In this work, silica aerogels derived from sodium silicate were prepared through a solvent-boiling strategy, where hydrophobization, solvent exchange, sodium purification, and ambient pressure drying (HSSA) proceeded successively and spontaneously in a one-pot process. This strategy leads to the synthesis of superhydrophobic silica aerogels with extremely low energy consumption without out the use of an ion-exchange resin or low surface tension solvents. Silica aerogels possess a high specific surface area (635 m 2 /g), high contact angle (153°), and low thermal conductivity (0.049 W/m K). A layer-by-layer (LBL) structure including the silica aerogel layer and an extra phase change material layer was designed. The structure demonstrates dual-functional thermal regulation performance in both harsh cold (−30 °C) and hot (70 °C) environments, where the time to reach equilibrium is postponed, and the inner temperature of the LBL structure can be kept above 20 °C in harsh cold environments (−30 °C) and below 31 °C in harsh hot environments (70 °C). A proof-of-concept experimental setup to simulate the illumination of sunlight also proved that the inside temperature of a model car protected by the LBL structure was below 28 °C, while the outside temperature was 70 °C. In addition, these results are well supported by theoretical COMSOL simulation results. The findings of this work not only provide an eco-friendly approach to synthesize silica aerogels but also demonstrate that the LBL structure is a robust dual-functional PTM system for thermal regulation in both harsh hot and cold environments.