Demonstrates enhanced formation of chiral organics in diazo compound reactions, suggesting efficient synthetic routes.
Transition metal catalyzed asymmetric synthesis enables access to valuable chiral organics, yet enantiopure catalysts remain challenging. In Research Article e5880430, Dmitry A. Loginov and co-workers present a concise four-step route to chiral rhodium(III) catalysts from naturally occurring (−)-α-pinene. These catalysts demonstrate broad utility in forming silanes, cyclopropanes, dihydroisoquinolones, and protoberberine alkaloids.
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Kharitonov et al. (2026) studied this question.
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