A diuranium( v ) bis-nitride complex supported by siloxide ligands displays remarkable reactivity in ambient conditions with small molecules such as CS ₂ , CO ₂ , CO and H ₂ resulting in N–C and N–H bond formation. The nitride linker also leads to an unusually strong antiferromagnetic coupling between uranium( v ) ions.
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Barluzzi et al. (2019) studied this question.
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