Experimental study demonstrates electrocatalytic aziridination of alkenes using tetrabutylammonium iodide, indicating a radical pathway without external conducting salt.
Efficient electrocatalytic aziridination of alkenes has been achieved for the first time. A structurally broad range of aziridines was easily accessed using an undivided cell operated at constant current and mediated by a catalytic quantity of n-Bu4NI. The electrocatalytic reaction also proceeded in the absence of additional conducting salt. The aziridination is proposed to follow a radical mechanism.
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Chen et al. (2015) studied this question.
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