The crystal structure of γ-cyclodextrin 13.3 hydrate was determined by the X-ray method on the basis of the data measured at room temperature. The γ-cyclodextrin molecule is in a round shape, and is slightly distorted from the regular octagonal structure. The γ-cyclodextrin cavity includes 5.3 water molecules which occupy the 13 sites.
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Kazuaki Harata (1984) studied this question.
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