The solid-state organization of a liquid crystalline metallosupramolecular polyelectrolyte−amphiphile complex at the nanoscopic level is decoded by a combination of X-ray scattering and molecular modeling. The nanostructured material, which self-assembles from transition metal ions, ditopic ligands, and amphiphiles, has a hierarchical architecture consisting of alternating strata of metallo units and interdigitated amphiphiles.
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Kurth et al. (2003) studied this question.
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