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An efficient catalytic system to oxidize quantitatively aliphatic diols using Trametes versicolor laccase and TEMPO has been developed in aqueous medium. Oxidations have occurred in a non‐stereoselective fashion but with complete regio‐ and/or monoselectivity, obtaining lactones with excellent purity after simple extraction. This catalytic system has been demonstrated to be scalable, compatible with the presence of a variety of functionalities, and also allowed the successful enzyme recycling using a laccase‐cross‐linked enzyme aggregates (CLEA) preparation.
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Díaz‐Rodríguez et al. (2012) studied this question.
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