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March 10, 2005Journal of the American Chemical Society

Reversible O−O Bond Cleavage and Formation of a Peroxo Moiety of a Peroxocarbonate Ligand Mediated by an Iron(III) Complex

Hideki Furutachi Koji Hashimoto Shigenori Nagatomo Taichi Endo Shuhei Fujinami Yoshihito Watanabe Teizo Kitagawa Masatatsu Suzuki

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Abstract

A mononuclear iron(III) complex containing a peroxocarbonate ligand, [Fe(qn)2(O2C(O)O)]- (qn = quinaldinate), underwent the reversible O-O bond cleavage and reformation of the peroxo group via the formation of FeIV=O or FeV=O species, which was confirmed by the resonance Raman and ESI-TOF/MS measurements.

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Furutachi et al. (2005) studied this question.

synapsesocial.com/papers/6a6ddbf975498292b7080165 https://doi.org/10.1021/ja0427202

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