A study concerning the synthesis of new N-heterocyclic carbene gold(I) complexes using the bis(trifluoromethanesulfonyl)imidate moiety (Tf 2 N - ) as a weakly coordinating counteranion is described. These new air-stable (NCH)AuNTf 2 complexes are convenient to prepare, stoe, and handle and proved to be active in a range of gold(I)-catalyzed transformations.
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Ricard et al. (2007) studied this question.
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