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The kinetics of Ag(I) ion catalysed oxidation of glycine by peroxodisulphate in aqueous medium has been studied. The reaction is found to be first order in peroxodisulphate and Ag(I) ions and almost independent of glycine concentration. The rate constant is found to decrease with the increase in the concentration of peroxodisulphate ion. Addition of neutral salts shows a retarding effect. A suitable mechanism has been proposed and a theoretical rate law has been derived to account for the results.
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Chandra et al. (1971) studied this question.
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