Rapid Stress Relaxation and Moderate Temperature of Malleability Enabled by the Synergy of Disulfide Metathesis and Carboxylate Transesterification in Epoxy Vitrimers

Vitrimers make up a class of polymeric materials combining the advantages of thermosets and thermoplastics, because they can be reprocessed while being at the same time permanently cross-linked. However, a long heating duration or an elevated temperature is necessary for most vitrimers to relax the stress from deformation and exhibit malleability. Herein, a disulfide-containing carboxylic acid is applied as a curing agent to synthesize epoxy vitrimers with simultaneous disulfide metathesis and carboxylate transesterification. The insoluble networks exhibit rapid stress relaxation and have relaxation times ranging from 1.5 s (200 °C) to 5500 s (60 °C), while the temperature of malleability is as low as 65 °C. Moreover, this vitrimer can be efficiently reprocessed at 100 °C in 1 h with full recovery of mechanical strength for at least four cycles. Additionally, such a material is simply synthesized from commercially available chemicals and may have potential applications in the electronics industry where a high temperature is not allowed.