Temperature and pH‐Dependent Swelling Behavior of Poly(N‐isopropylacrylamide) Copolymer Hydrogels and Their Use in Flow Control

Poly( N ‐isopropylacrylamide) (PNIPAAm) copolymer gels with acidic and basic comonomers of various molar ratios were prepared by radical polymerization. The relationship between the swelling behavior of the gels and the copolymerization ratio was studied experimentally at different temperatures and in various pH value buffer solutions. The results of the experiments revealed that the transition temperatures of the PNIPAAm copolymer gels were changed in proportion to the monomer ratio used in copolymerization. The pH value of the buffer solution strongly affected the swelling ratio and some of the transition temperatures of the gels. The PNIPAAm copolymer gels were used in a chemo‐mechanical valve. The liquid flows directly through a gel actuator, which consists of a cylindrical actuator chamber filled with small particles of the sensitive cross‐linked polymer. The flow rate as well as the pressure drop was measured in dependence on the solvent properties. With the presented experimental arrangement it could be shown that sensitive polymers can be used for controlling the flow in dependence on temperature and pH. pH‐Dependence of the pressure in a chemo‐mechanical valve. magnified image pH‐Dependence of the pressure in a chemo‐mechanical valve.