Macroscopic characterisation: The adsorption/desorption equilibrium of trioctylphosphine oxide ligands at colloidal InP nanocrystals (see picture) is investigated with quantitative, one-dimensional 1H NMR spectroscopy. Thermodynamic analysis of the isotherm demonstrates that formation of the capping is driven by favorable adsorbate–substrate interactions and is strengthened by adsorbate–adsorbate interactions.
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Moreels et al. (2006) studied this question.
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