A new strategy for preparation of 3-miktoarm star terpolymer was suggested. The fully-defined precursors PtBA-N3 (poly(tert-butyl acrylate) with azide end group), TEMPO-PEO or TEMPO-PCL (poly(ethylene oxide) or poly(ε-caprolactone) with TEMPO end group) and PS-alkyne/Br (polystyrene with ω-propargyl and ω′-(2-bromoiso butyryl) groups) are designed and prepared first, then the star terpolymers composed of PtBA, PS, and PEO (PCL) arms could be obtained via combination of “click chemistry” and ATNRC reaction using a one-pot. [Color figure can be viewed in the online issue, which is available at www.interscience.wiley.com.]
No takes yet. Share an insight, caveat, or question.
Fu et al. (2008) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: