Answers are grounded in this paper and cite their sources.
The presence of halide and pseudohalide anions dramatically affects the outcome of transition-metal catalysed reactions, both in terms of selectivity and activity. In this perspective, the roles and effects of these anionic ligands in topical and important Pd-catalysed cross-coupling reactions involving the formation of C–C bonds, e.g. Sonogashira, Stille and Suzuki–Miyaura cross-coupling, will be described. The use of imidate anions (derived from succinimide, maleimide and phthalimide) in several different classes of neutral and anionic Pd catalysts/precatalysts will be highlighted.
No takes yet. Share an insight, caveat, or question.
Fairlamb et al. (2006) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: