It's a flat world: Charge-neutral pincer-type cyclometalated platinum(II) aryl acetylides can be assembled into quasi-two-dimensional nanosheets through bilateral intermolecular noncovalent interactions (see picture). These nanosheets can be further self-organized into layered materials on a flat substrate and exhibit NIR phosphorescence and light-modulated conductivity.
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Chen et al. (2009) studied this question.
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