Using polystyrene-supported benzoquinone (PS–BQ) as cocatalyst with palladium chloride, the acetalization of terminal olefins with electron-withdrawing groups, i.e., acrylate esters, acrylonitrile, methyl vinyl ketone and acrolein, was carried out smoothly in supercritical carbon dioxide under oxygen atmosphere.
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Wang et al. (2005) studied this question.
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