Mineralization chemistry: Cu2P20 and Cu5InP16 were synthesized by a mineralization reaction from the elements and binary starting materials. Cu2P20 is the first representative retaining the structural features of violet or fibrous phosphorus in a binary compound (see picture). Cu5InP16 displays a previously unseen layered polyphosphide substructure built up of six-membered rings connected via four phosphorus bridges.
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Lange et al. (2008) studied this question.
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