From localized excited states to excitons: Changing of conceptions of primary photosynthetic processes in the twentieth century

A short description of two theories of the primary photosynthetic processes is given. Generally accepted in 1950s-1990s, the localized excited states theory has been changed to the modern exciton theory. Appearance of the new experimental data and the light-harvesting complex crystal structure are reasons why the exciton theory has become important. The bulk of data for the old theory and outstanding experiments that have been the driving force for a new theory are discussed in detail.