The essential similarity between interaction mechanisms for the 3d n , 4f n and 5f n series of paramagnetic ions in solids is emphasised. Some prevalent views of the relationship between parameter values and interaction mechanisms for 3d n ions are challenged. A unified model of the interaction processes is proposed and optimal parametrisation procedures for correlation crystal-field effects in 3d n ions are discussed.
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Newman et al. (1984) studied this question.
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