The synthesis of a variety of organotin compounds with 1 H , 1 H , 2 H , 2 H ‐perfluorooctyl groups is reported, together with an improved method for the corresponding distannoxane. Unique properties of this compound are disclosed in terms of fluorophilicity and activity as a Lewis acid catalyst in comparison with other mono‐nuclear derivatives. A new criterion for obtaining high solubility in fluorocarbon solvents is presented.
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Imakura et al. (2003) studied this question.
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