Calculation of the RamanGpeak intensity in monolayer graphene: role of Ward identities

The absolute integrated intensity of the single-phonon Raman peak at 1580 cm −1 is calculated for a clean graphene monolayer. The resulting intensity is determined by the trigonal warping of the electronic bands and the anisotropy of the electron–phonon coupling, and is proportional to the second power of the excitation frequency. The main contribution to the process comes from the intermediate electron-hole states with typical energies of the order of the excitation frequency, contrary to what has been reported earlier. This occurs because of strong cancellations between different terms of the perturbation theory, analogous to Ward identities in quantum electrodynamics.