A high-yield synthesis of atropoisomers of the meso-tetrakis(o-isonicotinoylamidophenyl)porphyrin was achieved. Depending on the crystallising solvent system, the α2β2 atropoisomer leads to the formation of either 1-D or 2-D coordination networks in the presence of Cu(OAc)2.
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Zimmer et al. (2002) studied this question.
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