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January 1, 1996Inorganic Chemistry

Cobaltmeso-Tetrakis(N-methyl-4-pyridiniumyl)porphyrin Becomes a Catalyst for the Electroreduction of O2by Four Electrons When (NH3)5Osn+(n= 2, 3) Groups Are Coordinated to the Porphyrin Ring

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CSChunnian ShiCalifornia Institute of TechnologyFAFred C. AnsonCalifornia Institute of Technology

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Shi et al. (1996) studied this question.

synapsesocial.com/papers/6a6fa0dc26a7f98052dc413bhttps://doi.org/10.1021/ic9607189
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  1. 1New Electrocatalysts for the Four-Electron Reduction of Dioxygen Based on (5,10,15-Tris(pentaammineruthenium(II)-4-cyanophenyl)-20- (1-methylpyridinium-4-yl)porphyrinato)cobalt(II) Immobilized on Graphite Electrodes1994 · 68 citations
  2. 2Evidence of the Importance of Back-Bonding in Determining the Behavior of Ruthenated Cyanophenyl Cobalt Porphyrins as Electrocatalysts for the Reduction of Dioxygen1995 · 44 citations
  3. 3.pi.-Heterocyclic complexes of pentaammineosmium(II) and the metal-induced cycloaddition of pyrrole and maleic anhydride1989 · 75 citations
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  5. 5Electrocatalysis of the reduction of molecular oxygen to water by tetraruthenated cobalt meso-tetrakis(4-pyridyl)porphyrin adsorbed on graphite electrodes1992 · 92 citations