A disk-shaped tridentate ligand 1 arranges silver(I) ions in a two-dimensional triangular and a three-dimensional tetrahedral fashion in the metal-ligand ratios, 3:2 and 1:1, respectively. The resulting sandwich-type (Ag312) and tetrahedral (Ag414) architectures are in a dynamic equilibrium in solution.
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Hiraoka et al. (2002) studied this question.
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