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The characterization of polyazulenes is reported with regard to two main aspects. First, results of circular dichroism spectroelectrochemistry of a carbohydrate‐modified azulene indicate that structural reorganization and chiroptical switching occur on oxidative doping. Second, the investigation of phenylene/azulene polymeric films with meta ‐ or para ‐phenylenes as bridging units provides information about electron transport and shows that phenylenic bridging allows structurally separated electron‐transfer‐active subunits to be created within the polymeric chain.
Porsch et al. (Tue,) studied this question.
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