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The enantioselective reaction of α-lithio benzyl 2-quinolyl sulfide proceeds through a dynamic thermodynamic resolution pathway, giving the products with high stereoselectivity. The products afford chiral thiols without racemization upon removal of the quinolyl group. (© Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)
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Nakamura et al. (2002) studied this question.
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